Research of the flocculation performance on diatomite with Sodium alginate and the hydroxamic Sodium alginate
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摘要: 以海藻酸钠为原料,通过非均相酯化反应和肟化反应,制备含氧肟酸基团的改性海藻酸钠高效絮凝剂。考察其对硅藻土的絮凝性能,结果表明:当沉降时间为30min,温度为20℃,海藻酸钠絮凝剂的投加量达到2.4mg/L时,去除率最大可达83.01%,而改性海藻酸钠絮凝剂投加量仅为0.8mg/L时,去除率最大可达91.53%,液固比为2.33,具有较好的絮凝效果。Abstract: Hydroxamated Sodium alginate with efficient flocculant were prepared by the successive heterogeneous esterification and hydroxamation of Sodium alginate under the certain conditions. And through the study on the flocculation performance of diatomite, the SA flocculant dosing quantity was carried out favorably with 2.4mg /L at20℃ for 30min in flocculant, the removal rate was 83.01%. The dosing quantity of the HSA with only 0.8mg /L, the removal rate was 91.53% and the ratio of liquid to solid was 2.33, and it had better characteristic in flocculant.
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Keywords:
- Sodium alginate /
- hydroxamic acid /
- flocculant /
- diatomite
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[1] Ho Chih Y, Strobel Eric, Ralbovsky Janet, et al.Improved Solution-and Solid-Phase Preparation of Hydroxamic Acids from Esters[J].J Org Chem, 2005, 70:4873-4875.
[2] 董放战.Hx型絮凝剂实验效果评价[J].轻金属, 2003 (9) :9-11. [3] 王秀娟, 张坤生, 任云霞, 等.海藻酸钠凝胶特性的研究[J].食品工业科技, 2008, 29 (2) :259-262. [4] 候金敏, 刘根起, 申娟娟.海藻酸钠的特性及其在水处理中的应用[J].材料开发与应用, 2012, 27 (3) :74-78. [5] 李海普, 梁璀, 李学明, 等.含异羟肟酸基团的高分子絮凝剂的制备[J].轻金属, 2010, (5) :19-24. [6] Lu Yaobo, Shang Yabo, Huang Xin, et al.Preparation of Strong Cationic Chitosan-graft-Polyacrylamide Flocculants and Their Flocculating Properties[J].Ind Eng Chem Res, 2011, 50 (12) :7141-7149.
[7] 肖力光, 赵壮, 于万增.硅藻土国内外发展现状及展望[J].吉林建筑工程学院学报, 2010, 27 (2) :26-30. [8] Gong Zailin, Tang Dongyan, Guo Yudi.The fabrication and self-flocculation effect of hybrid TiO2nanoparticles grafted with poly (N-isopropylacrylamide) at ambient temperature via surfaceinitiated atom transfer radical polymerization[J].J Mater Chem, 2012, 22:16872-16879.
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