Research advances on phthalate plasticizers detection methods in food
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摘要: 综述了近几年来食品中邻苯二甲酸酯类增塑剂在分析测定方法的研究进展,包括气相色谱法、气相色谱-质谱联用法、高效液相色谱法、高效液相色谱-串联质谱法、近红外光谱法、免疫分析方法。比较了各种方法的特点及应用情况,并对其发展趋势进行了展望,以期为邻苯二甲酸酯类增塑剂的分析提供参考依据。Abstract: Several phthalate plasticizers detection methods which applied widely, such as gas chromatography (GC) , gas chromatography-mass spectrometry (GC-MS) , high performance liquid chromatography (HPLC) , liquid chromatography-mass spectrometry (LC-MS) , near infrared spectroscopic (NIR) , immunological analysis (IA) were summarized. Characteristics and application conditions for each method were compared, and their trend of development were also prospected, expecting to provide several basis for phthalate plasticizers analysis.
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Keywords:
- food /
- plasticizers /
- phthalic acid esters /
- detection
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[1] Quintana J B, Rodil R, López-Mahía P, et al.Optimization of a selective method for the determination of organophosphorous triesters in outdoor particulate samples by pressurised liquid extraction and large-volume injection gas chromatographypositive chemical ionisation-tandem mass spectrometry[J].Analytical and Bioanalytical Chemistry, 2007, 388 (5-6) :1283-1293.
[2] Fasano E, Bono-Blay F, Cirillo T, et al.Migration of phthalates, alkylphenols, bisphenol A and di (2-ethylhexyl) adipate from food packaging[J].Food Control, 2012, 27 (1) :132-138.
[3] Skerra A, Pluckthurn A.Assembly of a functional immunoglobulin Fv fragment in Escherichia Coli[J].Science, 1988, 240:1038-1040.
[4] 肖乃玉, 陆杏春, 郭清兵, 等.塑料食品包装中邻苯二甲酸酯类增塑剂迁移研究进展[J].包装工程, 2010, 31 (11) :123-127. [5] 叶雅真, 朱宝平, 洪华荣, 等.2012年厦门市售婴幼儿配方奶粉及辅助食品中邻苯二甲酸酯类物质监测结果分析[J].中国卫生检验杂志, 2013, 23 (1) :218-219. [6] GB 9685-2008食品容器、包装材料用添加剂使用卫生标准[S]. [7] 柴丽月, 辛志宏, 蔡晶, 等.食品中邻苯二甲酸酯类增塑剂含量的测定[J].分析检测, 2008, 29 (7) :362-365. [7] 赵俊虹.气质联用法检测塑料包装西式火腿中邻苯二甲酸酯类增塑剂[J].粮油加工, 2010 (5) :131-133. [8] 李一尘, 徐静, 董伟峰, 等.气相色谱及气相色谱-质谱法检测食品中增塑剂[J].检验检疫学刊, 2012 (22) :40-57. [8] 杨琼, 张明时, 陈文生, 等.气相色谱法测定食用油脂中6种邻苯二甲酸酯类化合物[J].中国粮油学报, 2008, 23 (5) :171-174. [9] 李艳松, 陈铁英, 黄宝临, 等.食品中16种邻苯二甲酸酯类化合物的气相色谱测定方法[J].食品与机械, 2012, 28 (1) :105-107. [10] 王连珠, 王瑞龙, 刘溢娜, 等.分散固相萃取-气相色谱-质谱法测定罐头食品中6种邻苯二甲酸酯[J].理化检验, 2008, 44 (6) :502-506. [11] 杨悠悠, 谢云峰, 田菲菲, 等.常见食品中邻苯二甲酸酯类增塑剂含量及食品包装材料中邻苯二甲酸酯类增塑剂迁移量的测定[J].色谱, 2013, 31 (7) :674-678. [12] 郑向华, 林立毅, 方恩华, 等.固相萃取-气相色谱-质谱法测定食品中23种邻苯二甲酸酯[J].色谱, 2012, 30 (1) :27-32. [13] 卢春山, 李玮, 屠海云, 等.气相色谱-质谱联用测定食品中的邻苯二甲酸酯[J].分析测试学报, 2010, 29 (10) :1036-1040. [14] Sannino, Anna.Chromatographic/mass spectrometric method for determination of phthalates in oily foods[J].Journal of AOAC International, 2010, 93 (1) :315-322.
[15] Hanwen Sun, Yanlei Yang, Hui Li, et al.Development of multiresidue analysis for twenty phthalate esters in edible vegetable oils by microwave-assisted extraction-gel permeation chromatography-solid phase extraction-gas chromatographytandem mass spectrometry[J].Journal of Agricultural and Food Chemistry, 2012, 60 (22) :5532-5539.
[16] Sun Q J, Li L, Jiang Z L, et al.Characterization of phthalate plasticizer from bottled beverages by GC-MS[J].Applied Mechanics and Materials, 2013, 401:590-593.
[17] Li L, Sun Q J, Xin S G, et al.Detection of phthalate esters from plastic packaging materials into edible oil by gas chromatography-mass[J].Applied Mechanics and Materials, 2013, 395:355-358.
[18] 张春雨, 王辉, 张晓辉, 等.凝胶渗透色谱净化-高效液相色谱法测定油脂食品中的邻苯二甲酸酯类增塑剂[J].色谱, 2011 (29) :1236-1239. [19] 王美丽, 陈海婷, 张会娜, 等.高效液相色谱测定肉制食品中五种邻苯二甲酸酯[J].分析实验室, 2009, 28 (26) :49-52. [20] 王楠, 王伟, 张玉, 等.瓶装饮料中DNOP、DBP类增塑剂的液相色谱检测方法[J].中国食品学报, 2012, 12 (8) :179-185. [21] 张会军, 张敬轩, 李挥, 等.凝胶渗透色谱-高效液相色谱法对辣椒酱中14种邻苯二甲酸酯的同时检测[J].食品科学, 2011, 32 (4) :152-154. [22] Zhang C, Wang H, Zhang X, et al.Determination of phthalate plasticizers in foods by high performance liquid chromatography with gel permeation chromatographic clean-up[J].Chinese Journal of Chromatography, 2011, 29 (12) :1236-1239.
[23] 施雅梅, 徐敦明, 周昱, 等.QuEChERS/高效液相色谱测定食品中17种邻苯二甲酸酯[J].分析测试学报, 2011, 30 (12) :1372-1376. [24] 刘红河, 黄晓群, 王晖, 等.高效液相色谱-串联质谱法测定食品中邻苯二甲酸酯[J].现代预防医学, 2008, 35 (1) :119-121. [25] 袁永添, 刘正华, 李拥军, 等.高效液相色谱-串联质谱法同时测定牛奶中9种邻苯二甲酸酯[J].广东农业科学, 2012 (6) :100-108. [26] 岳丽君, 安代志, 王强, 等.某部食品中邻苯二甲酸酯类增塑剂检测情况[J].解放军预防医学杂志, 2013, 31 (2) :44-45. [27] 卓黎阳.超高效液相色谱-串联四极杆质谱测定酒中15种邻苯二甲酸酯[J].分析实验室, 2013, 32 (9) :68-73. [28] 刘杰, 郁宏燕, 鲍立杰, 等.液相色谱-串联质谱法测定饮料中16种邻苯二甲酸酯[J].食品科学, 2012, 33 (18) :211-215. [29] Xu D, Deng X, Fang E, et al.Determination of 23 phthalic acid esters in food by liquid chromatography tandem mass spectrometry[J].Journal of Chromatography A, 2014, 1324 (10) :49-56
[30] Chang-Liao W, Hou M, Chang L, et al.Determination and Pharmacokinetics of Di- (2-ethylhexyl) Phthalate in Rats by Ultra Performance Liquid Chromatography with Tandem Mass Spectrometry[J].Molecules, 2013, 18 (9) :11452-11466.
[31] 李祥辉, 杨方, 林振宇, 等.近红外光谱法应用于食用香精中增塑剂的检测研究[J].光谱学与光谱分析, 2013, 33 (3) :690-693. [32] Bouma K, Schakel D J.Migration of phthalates from PVC toys into saliva simulant by dynamic extraction[J].Food Additives&Contaminants, 2002, 19 (6) :602-610.
[33] 王运丽, 史新元, 吴志生, 等.利用近红外光谱技术快速检测邻苯二甲酸酯类物质[J].中国实验方剂学杂志, 2013, 19 (5) :86-90. [34] Zhao D, He L, Pu C, Deng AP.A highly sensitive and specific polyclonal antibody-based enzyme-linked immunosorbent assay for detection of antibiotic olaquindox in animal feed samples[J].Anal Bioanal Chem, 2008, 391:2653-2661.
[35] Estevez-Alberola MC, Marco MP.Immunochemical determination of xenobiotics with endocrine disrupting effects[J].Anal Bioanal Chem, 2004, 378:563-575.
[36] Shelver WL, Shappell NW, Franek M, et al.ELISA for sulfonamides and its application for screening in water contamination[J].Journal of Agricultural and Food Chemistry, 2008, 56 (15) :6609-6615.
[37] 胡玉嵘.食品中邻苯二甲酸二丙酯和邻苯二甲酸二丁酯的高灵敏免疫分析方法研究[D].安徽:安徽师范大学, 2012. [38] Zhang MC, Wang QE, Zhuang HS.A novel competitive fluorescenceimmunoassay for the determination of dibutyl phthalate[J].Anal Bioanal Chem, 2006, 386:1401-1406.
[39] Zhang MC, Wang QE, Zhuang HS.Determination of dibutyl o-phthalate by antigen-coated competitive fluorescence immunoassay[J].Anal Lett, 2007, 40:127-137.
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